I might be wrong, but I think two 580's can be set up so that the off-camera is a slave and the oncamera flash is a non-triggering master.
In the past, I've used a Sigma DG Super in Master mode, choosing the mode where the Master didn't contribute any light. I then set the 580 to slave. The Sigma did fire, but it was set low enough to not add any light to the scene. Worked in a pinch

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